994-89-8

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ETHYNYLTRI-n-BUTYLTIN, 95%

Product Code: SNE4900

Cas No: 994-89-8

10 g
$345.00
2.5 g
$107.00
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Organotin Cross-Coupling Agent

The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

Ethynyltri-n-butyltin; Tributylstannylacetylene
  • Undergoes reactions at triple bond
  • Pd catalyzed reactions with alkenyl and aryl iodides yields acetylenes
  • Transfer of ethynyl group
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011

    • Alternative Name: TRIBUTYLSTANNYLACETYLENE

    Specific Gravity: 1.092

    Flashpoint: 73°C (163°F)

    HMIS Key: 2-2-1-X

    Formula: C14H28Sn

    Purity: 95%

    Refractive Index: 1.4760

    Application: Undergoes reactions at triple bond.1
    Pd catalyzed reactions with alkenyl and aryl iodides yields acetylenes.2,3

    Reference: 1. Stamm, W. J. Org. Chem. 1963, 28, 3264.
    2. Stille, J. et al. J. Am. Chem. Soc. 1987, 109, 2138.
    3. Stille, J. et al. J. Org. Chem. 1989, 54, 5856.