14275-61-7

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BIS(TRI-n-BUTYLSTANNYL)ETHYLENE, trans isomer

Product Code: SNB1794

Cas No: 14275-61-7

R&D quantities:

5 g
$377.00
Organotin Cross-Coupling Agent

The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

trans-Bis(tri-n-butylstannyl)ethylene; Tributylstannylethyne
  • Used in the Michael addition of (E)-tributylstannylethylene unit to enones
  • β-Tri-n-butylstannylvinyl group or reagent for the formation of stilbenes
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011

    • Boiling Point: 185° / 0.01

    Molecular Weight: 606.11

    Specific Gravity: 1.150

    HMIS Key: 3-1-0-X

    Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions

    Formula: C26H56Sn2

    Refractive Index: 1.503

    Application: Used in the Michael addition of (E)-tributylstannylethylene unit to enones.1

    Reference: 1. Corey, E. et al. J .Am. Chem. Soc. 1974, 96, 5581.