TRIS(TRIMETHYLSILYL)PHOSPHINE, 10% in hexane

Product Code: SIT8723.4
CAS No: 15573-38-3
SDS Sheets: EU | US
Pack Size
Quantity
Price
 
10 g
$125.00
50 g
$495.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    4-4-2-X
  • Molecular Formula

    C9H27Psi3
  • Molecular Weight (g/mol)

    250.54
  • Boiling Point (˚C/mmHg)

    102-5° / 16
  • Density (g/mL)

    0.72
  • Flash Point (˚C)

    -23°C (-9°F)
  • Melting Point (˚C)

    24-6°, neat

Additional Properties

  • Hydrolytic Sensitivity

    8: reacts rapidly with moisture, water, protic solvents
  • Application

    Review of synthetic utility.1
    In combination with indium acetate forms InP quantum dots.2,3
    Promotes borylative dienylation/aldeyhyde coupling.4
    Reaction with methyllithium gives lithium bis(trimethylsilyl)phosphide,5 which reacts with dialkylformamides to give functional phosphaalkenes.6

    Reference

    1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 422-427.
    2. Bharal, D. et al. J. Am. Chem. Soc. 2005, 127, 11364.
    3. Kim, S. et al. J. Am. Chem. Soc. 2005, 127, 10526.
    4. Cho, H. Y.; Morken, J. P. J. Am. Chem. Soc. 2010, 132, 7576.
    5. Askham, F. R. et al. J. Am. Chem. Soc. 1985, 107, 7423.
    6. Prischenko, A. A. et al. Heteroatom. Chem. 2010, 21, 441.

    Safety

  • Packaging Under

    Nitrogen