76-86-8

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TRIPHENYLCHLOROSILANE, 95%

Product Code: SIT8645.0

Cas No: 76-86-8

R&D quantities:

100gm
$242.00
25gm
$75.00

Boiling Point: 188-9° / 3

EINECS Number: 200-989-0

Melting Point: 91-2°

Molecular Weight: 294.85

Specific Gravity: 1.16

Flashpoint: >200°C (>392°F)

HMIS Key: 3-1-1-X

Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents

Formula: C18H15ClSi

Purity: 95%

TSCA: TSCA

Application: Review of synthetic utility.1
Ether derivatives hydrolyze in acid at 0.25% the rate of corresponding Me3Si ethers.2
Reacts with AlBr3 and CO2 to directly form carboxylic acids from arenes and aryl halides.3
Used in the kinetic resolution of secondary alcohols.4
Used In an anion-relay approach to prepare sterically encumbered chiral binaphthols.5

Reference: 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 182-184.
2. Sommer, L. H. Stereochemistry, Mechanism and Silicon; McGraw-Hill: 1965; p. 126.
3. Nemoto, K. et al. J. Org. Chem. 2010, 75, 7855.
4. Sheppard, C. I. et al. Org. Lett. 2011, 13, 3794.
5. Maruoka, K. et al. Bull. Chem. Soc. Jpn. 1988, 61, 2975.

Additional Properties: Dipole moment: 2.14 debye
Contains triphenylsilanol