79265-30-8

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2-TRIMETHYLSILYLTHIAZOLE

Product Code: SIT8612.0

Cas No: 79265-30-8

R&D quantities:

5gm
$248.00

Boiling Point: 51-3° / 10

Molecular Weight: 157.31

Alternative Name: DONDONI REAGENT

Specific Gravity: 0.986

Flashpoint: 62°C (144°F)

HMIS Key: 2-3-1-X

Hydrolytic Sensitivity: 7: reacts slowly with moisture/water

Formula: C6H11NSSi

Refractive Index: 1.498

Application: Review of synthetic utility.1
Convenient substitute for 2-lithiothiazole for introducing various substituents at C-2 of the thiazole ring.2

Reference: 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 712-719.
2. Dondoni, A. et al. J. Org. Chem. 1988, 53, 1748.

Fieser: F&F: Vol. 16, p 362.