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2-(TRIMETHYLSILYL)PHENYLTRIFLUOROMETHANESULFONATE
Boiling Point: 70° / 2
Molecular Weight: 298.35
Specific Gravity: 1.229
Flashpoint: 96°C (205°F)
HMIS Key: 3-2-1-X
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Formula: C10H13F3O3SSi
Refractive Index: 1.456
Application: Review of synthetic utility.1
Used as a convenient source of in-situ-generated benzyne.2
Reference: 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 697-699.
2. Zhang, X.; Larock, R. C. Org. Lett. 2005, 7, 3973.
Silanes
Intermediate