16687-12-0

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TRIMETHYLSILYL PERRHENATE

Product Code: SIT8598.0

Cas No: 16687-12-0

R&D quantities:

2.5gm
$224.00

Boiling Point: 65-75° / 1 sub

Melting Point: 79-81°

Molecular Weight: 323.39

Alternative Name: TRIOXA(TRIMETHYLSILOXY)RHENIUM

HMIS Key: 2-1-1-X

Hydrolytic Sensitivity: 7: reacts slowly with moisture/water

Formula: C3H9O4ReSi

Application: Reacts with Me3SiOR to form ReO3(OR).1
Catalyzes Prins cyclization reaction between homoallylic alcohols and aldehydes.2

Reference: 1. Hermann, W. et al. Inorg. Chem. 1997, 36, 465.
2. Tadpetch, K.; Rychnovsky, S. D. Org. Lett. 2008, 10, 4839.

Additional Properties: Soluble: hydrocarbons, THF, chloroform; moisture sensitive