TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE, 1.0M in diethyl ether (19 wt %)

Product Code: SIT8594.0
CAS No: 13170-43-9
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13170-43-9
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100 g
$156.00
13 kg
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Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    3-4-2-X
  • Molecular Formula

    C4H11ClMgSi
  • Molecular Weight (g/mol)

    146.98
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    NA
  • Density (g/mL)

    0.777
  • Flash Point (˚C)

    -45 °C

Additional Properties

  • Hydrolytic Sensitivity

    8: reacts rapidly with moisture, water, protic solvents

    • Application

    Review of synthetic utility.1
    Promotes the conversion of alkyl halides to (E)-?-alkylstyrenes.2
    Highly useful inert ligand for the addition of Grignard reagents to aldehydes and ketones without enolization side reactions.3

    Fieser

    F&F: Vol. 6, p 636; Vol. 10, p 433; Vol. 15, p 343; Vol. 16, p 118; Vol. 18, p 384.

    Reference

    1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 666-674.
    2. Ikeda, Y. et al. J. Am. Chem. Soc. 2002, 124, 6514.
    3. Hatano, M. et al. J. Org. Chem. 2010, 75, 5008.

    Safety

  • Packaging Under

    Nitrogen