2-TRIMETHYLSILYL-1,3-DITHIANE

Product Code: SIT8589.0
CAS No: 13411-42-2
SDS Sheets: EU | US
Pack Size
Quantity
Price
 
5 g
$119.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    236-504-4
  • HMIS

    2-1-1-X
  • Molecular Formula

    C7H16S2Si
  • Molecular Weight (g/mol)

    192.42
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    85/1
  • Density (g/mL)

    1.014
  • Flash Point (˚C)

    96 °C
  • Refractive Index @ 20˚C

    1.5330

Additional Properties

  • Hydrolytic Sensitivity

    4: no reaction with water under neutral conditions
  • Application

    Review of synthetic utility.1
    Employed in synthesis of acylsilanes.2
    With BrF3 converts the oxygen of aldehydes and ketones to difluoromethyl groups.3
    Used in the preparation of acylsilanes.4
    Used in the preparation of unsaturated dithioketene acetals in a Peterson reaction.5
    Important reagent for Type I Anion Relay Chemistry (ARC).6

    Fieser

    F&F: Vol. 4, p 284; Vol. 10, p 380.

    Reference

    1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 604-609.
    2. Corey, E. J. et al. J. Am. Chem. Soc. 1967, 89, 434.
    3. Cohen, O. et al. Tetrahedron 2009, 65, 1361.
    4. Brinkmeyer, R. S. Tetrahedron Lett. 1979, 20, 207.
    5. Carey, F. A.; Court, A. S. J. Org. Chem. 1972, 37, 4474.
    6. Smith, A. B., III; Wuest, W. M. Chem. Commun. 2008, 5883.

    Safety

  • Packaging Under

    Nitrogen