2-(TRIMETHYLSILOXY)FURAN

Product Code: SIT8571.3
CAS No: 61550-02-5
Pack Size
Quantity
Price
 
5 g
$588.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    2-4-1-X
  • Molecular Formula

    C7H12O2Si
  • Molecular Weight (g/mol)

    156.26
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    40-42/25
  • Density (g/mL)

    0.950
  • Flash Point (˚C)

    18 °C
  • Refractive Index @ 20˚C

    1.436

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water
  • Application

    Review of synthetic utility.1
    Reviewed with other similar heterocycles.2
    Used in a vinylogous Mannich reaction to form aminomethyl butenolides.3
    Employed in asymmetric vinylogous aldol reaction with aldehydes.4
    Adds to allyl acetates to form 5-allyl-?-butenolides.5

    Reference

    1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 684-693.
    2. Casiraghi, G. et al. Synlett 2009, 1525.
    3. Akiyama, T. et al. Adv. Synth. Catal. 2008, 350, 399.
    4. Singh, R. P. et al. J. Am. Chem. Soc. 2010, 132, 9558.
    5. Cho, C.-W.; Krische, M. J. Angew. Chem., Int. Ed. Engl. 2004, 43, 6689.

    Safety

  • Packaging Under

    Nitrogen