2-(TRIMETHYLSILOXY)-1,3-BUTADIENE

Product Code: SIT8571.2
CAS No: 38053-91-7
SDS Sheets: EU | US
Pack Size
Quantity
Price
 
5 g
$90.00
25 g
$357.00
500 g
Contact Us For Pricing
14 kg
Contact Us For Pricing

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    3-4-1-X
  • Molecular Formula

    C7H14OSi
  • Molecular Weight (g/mol)

    144.27
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    50-55/50
  • Density (g/mL)

    0.807
  • Flash Point (˚C)

    12 °C
  • Refractive Index @ 20˚C

    1.4290

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water
  • Application

    Review of synthetic utility.1
    Undergoes photocyclization to 2-cycloalkenones, yielding bicyclic vinylcyclobutanols.2
    Copolymerizes with styrene using AIBN.3
    Useful Diels-Alder diene yielding substituted cyclohexanones.4

    Reference

    1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 681-684.
    2. Demuth, M. et al. Helv. Chim. Acta 1988, 71, 1392; F&F 15: 346.
    3. Penelle, J. et al. Polymer Preprints 1996, 37, 521.
    4. F&F: Vol. 7, p 401; Vol. 12, p 539.

    Safety

  • Packaging Under

    Nitrogen