1-(TRIMETHYLSILOXY)-1,3-BUTADIENE

Product Code: SIT8571.0
CAS No: 6651-43-0
SDS Sheets: EU | US
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6651-43-0
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Pack Size
Quantity
Price
 
25 g
$315.00

Prices listed are EXW price (Morrisville, PA US) in USD. Prices vary depending on currency and Incoterms.

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    2-3-1-X
  • Molecular Formula

    C7H14OSi
  • Molecular Weight (g/mol)

    142.27
  • Purity (%)

    97%
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    131
  • Density (g/mL)

    0.811
  • Flash Point (˚C)

    25 °C
  • Refractive Index @ 20˚C

    1.4480

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water

    • Application

    Review of synthetic utility.1
    Reacts with phenylsulfenyl chlorides at ?-position.2
    Used in efficient enantioselective synthesis of tamiflu.3
    Undergoes Diels-Alder reactions with high stereoselectivity.4

    Reference

    1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 677-680.
    2. Fleming, I. et al. Tetrahedron Lett. 1979, 20, 3205.
    3. Yamatsugu, K. et al. Angew. Chem., Int. Ed. Engl. 2009, 48, 1070.
    4. Rigby, J. H.; Kierkus, P. C. J. Am. Chem. Soc. 1989, 111, 4125.

    Safety

  • Packaging Under

    Nitrogen