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- HMIS 2-3-1-X
- Molecular Formula C7H14OSi
- Molecular Weight (g/mol) 142.27
- TSCA No
- Boiling Point (˚C/mmHg) 131
- Density (g/mL) 0.811
- Flash Point (˚C) 25 °C
- Refractive Index @ 20˚C 1.4480
Additional Properties
Application
Review of synthetic utility.1
Reacts with phenylsulfenyl chlorides at ?-position.2
Used in efficient enantioselective synthesis of tamiflu.3
Undergoes Diels-Alder reactions with high stereoselectivity.4
Reference
1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 677-680.
2. Fleming, I. et al. Tetrahedron Lett. 1979, 20, 3205.
3. Yamatsugu, K. et al. Angew. Chem., Int. Ed. Engl. 2009, 48, 1070.
4. Rigby, J. H.; Kierkus, P. C. J. Am. Chem. Soc. 1989, 111, 4125.
Safety
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