To search by structure, left click in the box below to display the chemdraw toolbar. Then, draw the chemical structure of interest in the box using the toolbar. When your structure is complete, click “Search by Name” or “Search by SMILES” to generate the product name or SMILES respectively. This feature will search within the Gelest product database for matching chemical names or SMILES. Note: In cases where Gelest uses alternate chemical names, it may be necessary to search for the product of interest by its CAS#.
All structures are computer generated. Please rely on the product data below for placing your order. If you see any errors in structures, please email customer service so that they can be addressed.
1-(TRIMETHYLSILOXY)-1,3-BUTADIENE
Boiling Point: 131°
Molecular Weight: 142.27
Specific Gravity: 0.811
Flashpoint: 25°C (77°F)
HMIS Key: 2-3-1-X
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Formula: C7H14OSi
Refractive Index: 1.4480
Application: Review of synthetic utility.1
Reacts with phenylsulfenyl chlorides at ?-position.2
Used in efficient enantioselective synthesis of tamiflu.3
Undergoes Diels-Alder reactions with high stereoselectivity.4
Reference: 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 677-680.
2. Fleming, I. et al. Tetrahedron Lett. 1979, 20, 3205.
3. Yamatsugu, K. et al. Angew. Chem., Int. Ed. Engl. 2009, 48, 1070.
4. Rigby, J. H.; Kierkus, P. C. J. Am. Chem. Soc. 1989, 111, 4125.
Silanes
Silanes
Silanes