2-(3-TRIETHOXYSILYLPHENYL)-1,3-DIOXOLANE

Product Code: SIT8185.9
CAS No: 1227828-43-4
SDS Sheets: EU | US
Pack Size
Quantity
Price
 
5 g
$303.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    2-2-1-X
  • Molecular Formula

    C15H24O5Si
  • Molecular Weight (g/mol)

    312.44

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water
  • Application

    Extensive review on the use in silicon-based cross-coupling reactions.1

    Reference

    1. Denmark, S. E. et al. Organic Reactions, Vol. 75, Denmark, S. E. ed., John Wiley and Sons, 233, 2011.

    Safety

  • Packaging Under

    Nitrogen
  • Arylsilane Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    2-(3-Triethoxysilylphenyl)-1,3-dioxolane

  • Useful for the preparation of benzaldehyde derivatives
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
  • Silicon Chemistry, Articles

    Silicon-Based Formation of Carbon-Carbon Bonds – Larson

    Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products