p-(TRIETHOXYSILYL)ACETOPHENONE, 95%

Product Code: SIT8177.0
CAS No: 438569-05-2
SDS Sheets: EU | US
Pack Size
Quantity
Price
 
2.5 g
$319.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    2-2-1-X
  • Molecular Formula

    C14H22O4Si
  • Molecular Weight (g/mol)

    282.41
  • Purity (%)

    95%
  • Boiling Point (˚C/mmHg)

    120° / 0.3
  • Density (g/mL)

    1.028
  • Density Temperature (˚C)

    25
  • Refractive Index @ 20˚C

    1.4727

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water
  • Safety

  • Packaging Under

    Nitrogen
  • Arylsilane Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    p-(Triethoxysilyl)acetophenone; [(p-Triethoxysilyl)phenyl]methylketone

  • Useful for preparation of acetophenone derivatives
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
  • Silicon Chemistry, Articles

    Silicon-Based Formation of Carbon-Carbon Bonds – Larson

    Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products