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SODIUM TRIMETHYLSILANOLATE, 96%
EINECS Number: 241-939-8
HMIS Key: 3-1-0-X
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
Formula: C3H9NaOSi
Purity: 96%
TSCA: TSCA
Application: Used as a weak base for alkylation of phenols.1
Directly generates amines from carboxylic acids in a modified Curtius reaction.2
Important promoter for silicon-based cross-coupling reactions.3
Reference: 1. Houpis, N. et al. Org. Lett. 2005, 7, 1947.
2. Ma, B.; Lee, C-W. Tetrahedron Lett. 2010, 51, 385.
3. Denmark, S. E. et al. Organic Reactions, Vol. 75, Denmark, S. E. ed., John Wiley and Sons, 233, 2011.
Silanes
Silanes