Additional Properties
- Einecs Number 241-939-8
- HMIS 3-1-0-X
- Molecular Formula C3H9NaOSi
- Molecular Weight (g/mol) 112.18
- Purity (%) 96%
- TSCA Yes
- Boiling Point (˚C/mmHg) NA
- Melting Point (˚C) 147-150° dec
Application
Used as a weak base for alkylation of phenols.1
Directly generates amines from carboxylic acids in a modified Curtius reaction.2
Important promoter for silicon-based cross-coupling reactions.3
Reference
1. Houpis, N. et al. Org. Lett. 2005, 7, 1947.
2. Ma, B.; Lee, C-W. Tetrahedron Lett. 2010, 51, 385.
3. Denmark, S. E. et al. Organic Reactions, Vol. 75, Denmark, S. E. ed., John Wiley and Sons, 233, 2011.
Safety