To search by structure, left click in the box below to display the chemdraw toolbar. Then, draw the chemical structure of interest in the box using the toolbar. When your structure is complete, click “Search by Name” or “Search by SMILES” to generate the product name or SMILES respectively. This feature will search within the Gelest product database for matching chemical names or SMILES. Note: In cases where Gelest uses alternate chemical names, it may be necessary to search for the product of interest by its CAS#.
All structures are computer generated. Please rely on the product data below for placing your order. If you see any errors in structures, please email customer service so that they can be addressed.
SODIUM TRIMETHYLSILANOLATE, 96%
EINECS Number: 241-939-8
Melting Point: 147-150° dec
Molecular Weight: 112.18
HMIS Key: 3-1-0-X
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
Formula: C3H9NaOSi
Purity: 96%
TSCA: TSCA
Application: Used as a weak base for alkylation of phenols.1
Directly generates amines from carboxylic acids in a modified Curtius reaction.2
Important promoter for silicon-based cross-coupling reactions.3
Reference: 1. Houpis, N. et al. Org. Lett. 2005, 7, 1947.
2. Ma, B.; Lee, C-W. Tetrahedron Lett. 2010, 51, 385.
3. Denmark, S. E. et al. Organic Reactions, Vol. 75, Denmark, S. E. ed., John Wiley and Sons, 233, 2011.
Silanes
Silanes