SODIUM TRIMETHYLSILANOLATE, 96%

Product Code: SIS6988.0
CAS No: 18027-10-6
SDS Sheets: EU | US
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18027-10-6
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Quantity
Price
 
25 g
$104.00
100 g
$335.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    241-939-8
  • HMIS

    3-1-0-X
  • Molecular Formula

    C3H9NaOSi
  • Molecular Weight (g/mol)

    112.18
  • Purity (%)

    96%
  • TSCA

    Yes
  • Boiling Point (˚C/mmHg)

    NA
  • Melting Point (˚C)

    147-150° dec

Additional Properties

  • Hydrolytic Sensitivity

    8: reacts rapidly with moisture, water, protic solvents

    • Application

    Used as a weak base for alkylation of phenols.1
    Directly generates amines from carboxylic acids in a modified Curtius reaction.2
    Important promoter for silicon-based cross-coupling reactions.3

    Reference

    1. Houpis, N. et al. Org. Lett. 2005, 7, 1947.
    2. Ma, B.; Lee, C-W. Tetrahedron Lett. 2010, 51, 385.
    3. Denmark, S. E. et al. Organic Reactions, Vol. 75, Denmark, S. E. ed., John Wiley and Sons, 233, 2011.

    Safety

  • Packaging Under

    Nitrogen