879904-87-7

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SODIUM (2-THIENYL)DIMETHYLSILANOLATE, 2M in methyltetrahydrofuran

Product Code: SIS6987.0

Cas No: 879904-87-7

R&D quantities:

10 g
$241.00
Arylsilane Cross-Coupling Agent

The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

Sodium (4-methylphenyl)dimethylsilanolate
  • Sodium silanolate generated “in-situ”
  • 2 M in Tetrahydrofuran
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
  • Molecular Weight: 180.31

    Specific Gravity: 0.961

    Flashpoint: -14°C (7°F)

    HMIS Key: 2-4-1-X

    Hydrolytic Sensitivity: 5: forms reversible hydrate

    Formula: C6H9NaOSSi

    Application: Sodium silanolate generated "in-situ".1

    Reference: 1. Denmark, S. E.; Baird, J. D. Org. Lett. 2006, 8, 793.