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- HMIS 2-4-1-X
- Molecular Formula C6H9NaOSSi
- Molecular Weight (g/mol) 180.31
- TSCA No
- Boiling Point (˚C/mmHg) NA
- Density (g/mL) 0.961
- Flash Point (˚C) -14 °C
Additional Properties
Application
Sodium silanolate generated "in-situ".1
Reference
1. Denmark, S. E.; Baird, J. D. Org. Lett. 2006, 8, 793.
Safety
Arylsilane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Sodium (4-methylphenyl)dimethylsilanolate
Silicon Chemistry, Articles
Silicon-Based Formation of Carbon-Carbon Bonds – Larson
Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products
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