SODIUM (2-FURYL)DIMETHYLSILANOLATE

Product Code: SIS6980.6
CAS No: 879904-88-8
Pack Size
Quantity
Price
 
10 g
$383.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    3-3-1-X
  • Molecular Formula

    C6H9NaO2Si
  • Molecular Weight (g/mol)

    164.24
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    NA
  • Melting Point (˚C)

    65-80°

Additional Properties

  • Hydrolytic Sensitivity

    5: forms reversible hydrate
  • Safety

  • Packaging Under

    Nitrogen
  • Arylsilane Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    Sodium (2-furyl)dimethylsilanolate; Sodium 2-furanyldimethylsilanolate

  • 2 M in Tetrahydrofuran
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
  • Silicon Chemistry, Articles

    Silicon-Based Formation of Carbon-Carbon Bonds – Larson

    Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products