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SODIUM BIS(TRIMETHYLSILYL)AMIDE, 95%
Boiling Point: 202° / 1-2
EINECS Number: 213-983-8
Melting Point: 165-7°
Molecular Weight: 183.37
Alternative Name: N-SODIOHEXAMETHYLDISILAZANE
HMIS Key: 3-3-1-X
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
Application: Review of synthetic utility.1
Reacts with allyl chloride in toluene to form cyclopropene.2
Reference: 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 468-478.
2. Binger, P. et al. Org. Synth. 1999, 77, 254.
Fieser: F&F: Vol. 1, p 1046; Vol. 3, p 261; Vol. 6, p 442; Vol. 7, p 329; Vol. 12, p 441, p 446; Vol. 16, p 307; Vol. 21, p 401.
Additional Properties: Soluble: hexane, toluene, ether, THF