SODIUM ALLYLDIMETHYLSILANOLATE, 2M in tetrahydrofuran

Product Code: SIS6977.0
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Price
 
10 g
$298.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    2-4-1-X
  • Molecular Formula

    C5H11NaOSi
  • Molecular Weight (g/mol)

    138.22
  • Boiling Point (˚C/mmHg)

    NA
  • Flash Point (˚C)

    -14 °C

Additional Properties

  • Hydrolytic Sensitivity

    5: forms reversible hydrate

    • Application

    Extensive review on the use in silicon-based cross-coupling reactions.1

    Reference

    1. Denmark, S. E. et al. Organic Reactions, Vol. 75, Denmark, S. E. ed., John Wiley and Sons, 233, 2011.

    Safety

  • Packaging Under

    Nitrogen

    • Arylsilane Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    Sodium allyldimethylsilanolate

  • 2 M in Tetrahydrofuran
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011

    • Silicon Chemistry, Articles

    Silicon-Based Formation of Carbon-Carbon Bonds – Larson

    Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products