(2-PYRIDYL)ALLYLDIMETHYLSILANE, 90%

Product Code: SIP6923.0
CAS No: 118722-54-6
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118722-54-6
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Quantity
Price
 
2.5 g
$304.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    3-2-1-X
  • Molecular Formula

    C10H15NSi
  • Molecular Weight (g/mol)

    177.32
  • Purity (%)

    90%
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    104-105/18
  • Flash Point (˚C)

    71 °C
  • Refractive Index @ 20˚C

    1.5046

Additional Properties

  • Hydrolytic Sensitivity

    4: no reaction with water under neutral conditions

    • Application

    Allylates ketones and aldehydes in the absence of palladium catalysis. Source for other 2- pyridyl allylsilanes.1
    Extensive review on the use in silicon-based cross-coupling reactions.2

    Reference

    1. Kamei, T. et al. Org. Lett. 2005, 7, 4725.
    2. Denmark, S. E. et al. Organic Reactions, Vol. 75, Denmark, S. E. ed., John Wiley and Sons, 233, 2011.

    Safety

  • Packaging Under

    Nitrogen
  • Store Below 5 ˚C

    • Arylsilane Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    (2-Pyridyl)allyldimethylsilane; (2-Allyldimethylsilyl)pyridine

  • Water and air-stable arylsilane for formation of 2-aryl pyridines
  • Allylates aldehydes, ketones and imines
  • Allylates ketones and aldehydes in the absence of palladium catalysis
  • Source for other 2- pyridyl allylsilanes
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011