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Arylsilane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Flashpoint: 71°C (160F)
HMIS Key: 3-2-1-X
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
Refractive Index: 1.5046
Application: Allylates ketones and aldehydes in the absence of palladium catalysis. Source for other 2- pyridyl allylsilanes.1
Extensive review on the use in silicon-based cross-coupling reactions.2
Reference: 1. Kamei, T. et al. Org. Lett. 2005, 7, 4725.
2. Denmark, S. E. et al. Organic Reactions, Vol. 75, Denmark, S. E. ed., John Wiley and Sons, 233, 2011.