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- Synonyms ISOPROPENYLTRIMETHYLSILANE
- HMIS 2-4-0-X
- Molecular Formula C6H14Si
- Molecular Weight (g/mol) 114.26
- Purity (%) 95%
- TSCA No
- Boiling Point (˚C/mmHg) 83°
- Density (g/mL) 0.72
- Flash Point (˚C) -12°C (10°F)
- Refractive Index @ 20˚C 1.4061
Additional Properties
Application
For introduction of the 2-propenyl group via cross-coupling.1
Reference
1. Larson, G. L. “Silicon-Based Cross-Coupling Reagents” Gelest, Inc. 2011.
Safety
Alkenylsilane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
2-Propenyltrimethylsilane; 2-Trimethylsilylprop-1-ene; Isopropenyltrimethylsilane
Silicon Chemistry, Articles
Silicon Chemistry, Articles
Silicon-Based Formation of Carbon-Carbon Bonds – Larson
Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products
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