2-PROPENYLTRIMETHYLSILANE, 92%

Product Code: SIP6905.0
CAS No: 18163-07-0
SDS Sheets: EU | US
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18163-07-0
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5 g
$272.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Synonyms

    ISOPROPENYLTRIMETHYLSILANE
  • HMIS

    2-4-0-X
  • Molecular Formula

    C6H14Si
  • Molecular Weight (g/mol)

    114.26
  • Purity (%)

    92%
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    83
  • Density (g/mL)

    0.72
  • Flash Point (˚C)

    -12 °C
  • Refractive Index @ 20˚C

    1.4061

Additional Properties

  • Hydrolytic Sensitivity

    1: no significant reaction with aqueous systems

    • Application

    For introduction of the 2-propenyl group via cross-coupling.1

    Reference

    1. Larson, G. L. “Silicon-Based Cross-Coupling Reagents” Gelest, Inc. 2011.

    Safety

  • Packaging Under

    Nitrogen

    • Alkenylsilane Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    2-Propenyltrimethylsilane; 2-Trimethylsilylprop-1-ene; Isopropenyltrimethylsilane

  • For introduction of the 2-propenyl group via cross-coupling
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011

    • Silicon Chemistry, Articles

    α, β-Epoxysilanes – Hudrlik et al.

    Silicon Chemistry, Articles

    Silicon-Based Formation of Carbon-Carbon Bonds – Larson

    Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products