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- HMIS 3-2-1-X
- Molecular Formula C6H15KOSi
- Molecular Weight (g/mol) 170.37
- Purity (%) 95%
- TSCA No
- Boiling Point (˚C/mmHg) NA
Additional Properties
Application
Used as a nucleophiles in the enantioselective formation of allyl alcohols from allyl carbonates.1
Employed in an inexpensive vinylation of aryl bromides.2
Catalyst for the cross-coupling of aryl and vinylsilanes.3
Reference
1. Lyothier, I. et al. Angew. Chem., Int. Ed. Engl. 2006, 45, 6204.
2. Denmark, S. E.; Butler, C.R. J. Am. Chem. Soc. 2008, 130, 3690.
3. Jeffery, T. Tetrahedron Lett. 1999, 40, 1673.
Safety
Silane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Potassium triethylsilanolate; Potassium triethylsiloxide; Triethylsilanol, potassium salt
Silicon Chemistry, Articles
Silicon-Based Formation of Carbon-Carbon Bonds – Larson
Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products
