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- HMIS 3-4-1-X
- Molecular Formula C6H5F3Si
- Molecular Weight (g/mol) 162.19
- Purity (%) 95%
- Boiling Point (˚C/mmHg) 101-2°
- Density (g/mL) 1.2169
- Flash Point (˚C) -5°C (23°F)
- Melting Point (˚C) -19°
- Refractive Index @ 20˚C 1.4110
Catalyzes the reaction of trimethylsilylmethyl imidates with dipolarophiles.1
1. Washizuka, K. et al. Tetrahedron 1999, 55, 12969.
Arylsilane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Silicon Chemistry, Articles
Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products