PHENYLTHIOTRIMETHYLSILANE

Product Code: SIP6770.0
CAS No: 4551-15-9
SDS Sheets: EU | US
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4551-15-9
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Price
 
25 g
$183.00

Prices listed are EXW price (Morrisville, PA US) in USD. Prices vary depending on currency and Incoterms.

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    224-916-7
  • HMIS

    3-3-1-X
  • Molecular Formula

    C9H14SSi
  • Molecular Weight (g/mol)

    182.36
  • Purity (%)

    97%
  • TSCA

    Yes
  • Boiling Point (˚C/mmHg)

    72/8
  • Density (g/mL)

    0.963
  • Flash Point (˚C)

    33 °C
  • Refractive Index @ 20˚C

    1.5320

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water

    • Application

    Review of synthetic utility.1
    Converts adehydes to phenylsulfides.2
    Converts aromatic aldehydes to coupled diols with Yb metal.3
    Reacts w/ aryl fluorides to provide phenylaryl thioethers.4
    Converts enol silyl ethers into vinylsulfides.5

    Fieser

    F&F: Vol. 10, p 426; Vol. 12, p 535; Vol. 16, p 278.

    Reference

    1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 414-418.
    2. Glass, R. Synth. Commun. 1976, 6, 47.
    3. Fujiwara, Y. et al. Tetrahedron Lett. 1996, 37. 3465.
    4. Liu, C. et al. Synlett 2011, 22, 1143.
    5. Degl’innocenti, A. et al. Synlett.1992, 499.

    Safety

  • Packaging Under

    Nitrogen