PHENYLTHIOTRIMETHYLSILANE

Product Code: SIP6770.0
CAS No: 4551-15-9
SDS Sheets: EU | US
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4551-15-9
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Quantity
Price
 
25 g
$183.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    224-916-7
  • HMIS

    3-3-1-X
  • Molecular Formula

    C9H14SSi
  • Molecular Weight (g/mol)

    182.36
  • TSCA

    Yes
  • Boiling Point (˚C/mmHg)

    72/8
  • Density (g/mL)

    0.963
  • Flash Point (˚C)

    33 °C
  • Refractive Index @ 20˚C

    1.5320

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water

    • Application

    Review of synthetic utility.1
    Converts adehydes to phenylsulfides.2
    Converts aromatic aldehydes to coupled diols with Yb metal.3
    Reacts w/ aryl fluorides to provide phenylaryl thioethers.4
    Converts enol silyl ethers into vinylsulfides.5

    Fieser

    F&F: Vol. 10, p 426; Vol. 12, p 535; Vol. 16, p 278.

    Reference

    1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 414-418.
    2. Glass, R. Synth. Commun. 1976, 6, 47.
    3. Fujiwara, Y. et al. Tetrahedron Lett. 1996, 37. 3465.
    4. Liu, C. et al. Synlett 2011, 22, 1143.
    5. Degl’innocenti, A. et al. Synlett.1992, 499.

    Safety

  • Packaging Under

    Nitrogen