PHENYLSELENOTRIMETHYLSILANE, 95%

Product Code: SIP6747.0
CAS No: 33861-17-5
Pack Size
Quantity
Price
 
5 g
$363.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Synonyms

    PHENYLTRIMETHYLSILYLSELENIDE
  • HMIS

    3-2-1-X
  • Molecular Formula

    C9H14SeSi
  • Molecular Weight (g/mol)

    229.26
  • Purity (%)

    95%
  • Boiling Point (˚C/mmHg)

    92-3° / 5
  • Density (g/mL)

    1.196
  • Melting Point (˚C)

    -5°
  • Refractive Index @ 20˚C

    1.5525

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water
  • Application

    Review of synthetic utility.1
    Catalytic radical initiator for alkylselenation and other radical reactions.2
    Asymmetrically opens epoxides.3
    Regio- and stereoselectively adds to acetylenes under palladium catalysis.4

    Fieser

    F&F: Vol. 9, p 373.

    Reference

    1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 421-422.
    2. Pandey, G. et al. J. Org. Chem. 2000, 65, 4309.
    3. Tiecco, M. et al. Tetrahedron 2008, 64, 3337.
    4. Detty, M. R. J. Org. Chem. 1979, 44, 4528.

    Safety

  • Packaging Under

    Nitrogen