(S,S)-2-PHENYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE

Product Code: SIP6724.95
CAS No: 680592-40-9
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680592-40-9
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Pack Size
Quantity
Price
 
5 g
$183.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Synonyms

    1-OXA-3-AZA-2-SILACYCLOPENTANE, 2-CHLORO-3,4-DIMETHYL-5-PHENYL-2,5-DIPHENYL, (4S,5S)
  • HMIS

    2-2-1-X
  • Molecular Formula

    C16H18ClNOSi
  • Molecular Weight (g/mol)

    303.86
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    138/0.5
  • Density (g/mL)

    1.016

Additional Properties

  • Hydrolytic Sensitivity

    8: reacts rapidly with moisture, water, protic solvents

    • Application

    Catalyzes the enantioselective Friedel-Crafts alkylation of benzoylhydrazones.1
    Promotes a tandem asymmetric Aza-Darzens-ring-opening reaction to ?-amino-?-chloro esters and ?-amino-?-aryl esters.2

    Reference

    1. Shirakawa, S. et al. J. Am. Chem. Soc. 2005, 127, 2858
    2. Valdez, S. C.; Leighton, J. L. J. Am. Chem. Soc. 2009, 131, 14638.

    Safety

  • Packaging Under

    Nitrogen