1-NAPHTHYLTRIETHOXYSILANE

Product Code: SIN6596.8
CAS No: 17938-06-6
SDS Sheets: EU | US
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17938-06-6
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Quantity
Price
 
5 g
$311.00

Prices listed are EXW price (Morrisville, PA US) in USD. Prices vary depending on currency and Incoterms.

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    2-1-1-X
  • Molecular Formula

    C16H22O3Si
  • Molecular Weight (g/mol)

    290.43
  • Purity (%)

    95%
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    121-123/0.1
  • Density (g/mL)

    1.0476
  • Density Temperature (˚C)

    25
  • Flash Point (˚C)

    >110 °C
  • Refractive Index @ 20˚C

    1.5273

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water

    • Safety

  • Packaging Under

    Nitrogen

    • Arylsilane Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    1-Naphthyltriethoxysilane; 1-(Triethoxysilane)naphthalene

  • Undergoes asymmetric coupling w/ α-bromoesters
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011

    • Silicon Chemistry, Articles

    Silicon-Based Formation of Carbon-Carbon Bonds – Larson

    Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products