1-NAPHTHYLTRIETHOXYSILANE

Product Code: SIN6596.8
CAS No: 17938-06-6
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17938-06-6
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Quantity
Price
 
5 g
$311.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    2-1-1-X
  • Molecular Formula

    C16H22O3Si
  • Molecular Weight (g/mol)

    290.43
  • Purity (%)

    95%
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    121-3° / 0.1
  • Density (g/mL)

    1.0476
  • Density Temperature (˚C)

    25
  • Flash Point (˚C)

    >110 °C
  • Refractive Index @ 20˚C

    1.5273

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water

    • Safety

  • Packaging Under

    Nitrogen

    • Arylsilane Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    1-Naphthyltriethoxysilane; 1-(Triethoxysilane)naphthalene

  • Undergoes asymmetric coupling w/ α-bromoesters
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011

    • Silicon Chemistry, Articles

    Silicon-Based Formation of Carbon-Carbon Bonds – Larson

    Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products