3,4-METHYLENEDIOXYPHENYLTRIETHOXYSILANE

Product Code: SIM6509.0
CAS No: 376353-50-3
SDS Sheets: EU | US
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376353-50-3
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Pack Size
Quantity
Price
 
2.5 g
$348.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    2-2-1-X
  • Molecular Formula

    C13H20O5Si
  • Molecular Weight (g/mol)

    284.38
  • Purity (%)

    95%
  • TSCA

    No

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water

    • Safety

  • Packaging Under

    Nitrogen

    • Arylsilane Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    3,4-Methylenedioxyphenyltriethoxysilane; 5-(Triethoxysilyl)-1,3-benzodioxole; 1-Triethoxysilyl-3,4-methylendioxybenzene; 4-(Triethoxysilyl)-1,2-(methylenedioxy)benzene

  • Used in the coupling to allyl carbonates and allyl benzoates.
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011

    • Silicon Chemistry, Articles

    Silicon-Based Formation of Carbon-Carbon Bonds – Larson

    Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products