1-METHOXY-3-(TRIMETHYLSILOXY)BUTADIENE, 85%

Product Code: SIM6494.0
CAS No: 54125-02-9
SDS Sheets: EU | US
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54125-02-9
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Pack Size
Quantity
Price
 
5 g
$245.00

Prices listed are EXW price (Morrisville, PA US) in USD. Prices vary depending on currency and Incoterms.

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Synonyms

    DANISHEFSKY'S DIENE
  • HMIS

    2-2-1-X
  • Molecular Formula

    C8H16O2Si
  • Molecular Weight (g/mol)

    172.30
  • Purity (%)

    85%
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    68-69/14
  • Density (g/mL)

    0.885
  • Flash Point (˚C)

    45 °C
  • Refractive Index @ 20˚C

    1.4545

Additional Properties

  • Hydrolytic Sensitivity

    8: reacts rapidly with moisture, water, protic solvents

    • Application

    Diels-Alder cyclohexenone building block.1
    Asymmetrically adds to aldehydes.2
    Cycloadds with high ee values to n-butylglyoxylate.3
    Reacts with imines to give optically active 6-substituted piperidenones.4

    Reference

    1. Danishefsky, S. Acc. Chem. Res. 1981, 14, 400.
    2. Furuno, H. et al. Org. Lett. 2000, 2, 49.
    3. Motoyama, Y. et al. Tetrahedron 2001, 57, 853.
    4. Mancheño, O. G. et al. J. Am. Chem. Soc. 2004, 126, 456.

    Safety

  • Packaging Under

    Nitrogen
  • Store Below 5 ˚C