p-METHOXYPHENYLTRIETHOXYSILANE

Product Code: SIM6492.53
CAS No: 21130-91-6
SDS Sheets: EU | US
Pack Size
Quantity
Price
 
5 g
$99.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    2-2-1-X
  • Molecular Formula

    C13H22O4Si
  • Molecular Weight (g/mol)

    270.40
  • Boiling Point (˚C/mmHg)

    91-2° / 0.15
  • Density (g/mL)

    1.018
  • Density Temperature (˚C)

    25
  • Flash Point (˚C)

    >65°C (>150°F)
  • Refractive Index @ 20˚C

    1.471

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water
  • Safety

  • Packaging Under

    Nitrogen
  • Arylsilane Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    p-Methoxyphenyltriethoxysilane; 4-Triethoxysilylanisole; (p-Anisyl)triethoxysilane; 4-(Triethoxysilyl)anisole; 1-Triethoxysilyl-4-methoxybenzene; 1-Methoxy-4-(triethoxysilyl)benzene

  • Undergoes conjugate addition to enones
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
  • Silicon Chemistry, Articles

    Silicon-Based Formation of Carbon-Carbon Bonds – Larson

    Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products