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- Einecs Number 222-201-4
- Synonyms BIS(TRIMETHYLSILYL)SULFIDE
- HMIS 3-3-1-X
- Molecular Formula C6H18SSi2
- Molecular Weight (g/mol) 178.45
- TSCA Yes
- Boiling Point (˚C/mmHg) 162-4°
- Density (g/mL) 0.851
- Flash Point (˚C) 26°C (79°F)
- Refractive Index @ 20˚C 1.4598
Additional Properties
Application
Reviews.1,2
Used in the generation of SAMs of alkanethiolates on noble metal surfaces.3
Forms glycosyl sulfides.4
Opens epoxides regioselectively to form ?-mercaptoethanols.5
Reference
1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 83-84.
2. McGregor, W. et al. Chem. Soc. Rev. 1993, 199.
3. Hu, J.; Fox, M. A. J. Org. Chem. 1999, 64, 4959.
4. Dere, R. T. et al. J.Org. Chem. 2011, 76, 7539.
5. Degl’Innocenti, A. et al. Tetrahedron Lett. 1993, 34, 873.
Safety
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