HEXAMETHYLDISILTHIANE

Product Code: SIH6116.0
CAS No: 3385-94-2
SDS Sheets: EU | US
Pack Size
Quantity
Price
 
5 g
$159.00

Prices listed are EXW price (Morrisville, PA US) in USD. Prices vary depending on currency and Incoterms.

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    222-201-4
  • Synonyms

    BIS(TRIMETHYLSILYL)SULFIDE
  • HMIS

    3-3-1-X
  • Molecular Formula

    C6H18SSi2
  • Molecular Weight (g/mol)

    178.45
  • Purity (%)

    97%
  • TSCA

    Yes
  • Boiling Point (˚C/mmHg)

    162-4°
  • Density (g/mL)

    0.851
  • Flash Point (˚C)

    26 °C
  • Refractive Index @ 20˚C

    1.4598

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water
  • Application

    Reviews.1,2
    Used in the generation of SAMs of alkanethiolates on noble metal surfaces.3
    Forms glycosyl sulfides.4
    Opens epoxides regioselectively to form ?-mercaptoethanols.5

    Reference

    1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 83-84.
    2. McGregor, W. et al. Chem. Soc. Rev. 1993, 199.
    3. Hu, J.; Fox, M. A. J. Org. Chem. 1999, 64, 4959.
    4.  Dere, R. T. et al. J.Org. Chem. 2011, 76, 7539.
    5. Degl’Innocenti, A. et al. Tetrahedron Lett. 1993, 34, 873.

    Safety

  • Packaging Under

    Nitrogen