HEXAMETHYLDISILTHIANE

Product Code: SIH6116.0
CAS No: 3385-94-2
SDS Sheets: EU | US
Navigate this page...
3385-94-2
Save for Later
Pack Size
Quantity
Price
 
5 g
$159.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    222-201-4
  • Synonyms

    BIS(TRIMETHYLSILYL)SULFIDE
  • HMIS

    3-3-1-X
  • Molecular Formula

    C6H18SSi2
  • Molecular Weight (g/mol)

    178.45
  • Purity (%)

    97%
  • TSCA

    Yes
  • Boiling Point (˚C/mmHg)

    162-4°
  • Density (g/mL)

    0.851
  • Flash Point (˚C)

    26 °C
  • Refractive Index @ 20˚C

    1.4598

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water

    • Application

    Reviews.1,2
    Used in the generation of SAMs of alkanethiolates on noble metal surfaces.3
    Forms glycosyl sulfides.4
    Opens epoxides regioselectively to form ?-mercaptoethanols.5

    Reference

    1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 83-84.
    2. McGregor, W. et al. Chem. Soc. Rev. 1993, 199.
    3. Hu, J.; Fox, M. A. J. Org. Chem. 1999, 64, 4959.
    4.  Dere, R. T. et al. J.Org. Chem. 2011, 76, 7539.
    5. Degl’Innocenti, A. et al. Tetrahedron Lett. 1993, 34, 873.

    Safety

  • Packaging Under

    Nitrogen