3385-94-2

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HEXAMETHYLDISILTHIANE

Product Code: SIH6116.0

Cas No: 3385-94-2

R&D quantities:

5 g
$132.00

Boiling Point: 162-4°

EINECS Number: 222-201-4

Molecular Weight: 178.45

Alternative Name: BIS(TRIMETHYLSILYL)SULFIDE

Specific Gravity: 0.851

Flashpoint: 26°C (79°F)

HMIS Key: 3-3-1-X

Hydrolytic Sensitivity: 7: reacts slowly with moisture/water

Formula: C6H18SSi2

Refractive Index: 1.4598

TSCA: TSCA

Application: Reviews.1,2
Used in the generation of SAMs of alkanethiolates on noble metal surfaces.3
Forms glycosyl sulfides.4
Opens epoxides regioselectively to form ?-mercaptoethanols.5

Reference: 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 83-84.
2. McGregor, W. et al. Chem. Soc. Rev. 1993, 199.
3. Hu, J.; Fox, M. A. J. Org. Chem. 1999, 64, 4959.
4.  Dere, R. T. et al. J.Org. Chem. 2011, 76, 7539.
5. Degl’Innocenti, A. et al. Tetrahedron Lett. 1993, 34, 873.

Fieser:

Additional Properties: Dipole moment: 1.85 debye
Stench