261717-41-3

All structures are computer generated. Please rely on the product data below for placing your order. If you see any errors in structures, please email customer service so that they can be addressed.

(E)-HEPTENYLDIISOPROPYLSILANOL

Product Code: SIH5844.5

Cas No: 261717-41-3

R&D quantities:

2.5gm
$379.00

Interested in a Commercial Order?

Boiling Point: 88° / 0.1

Molecular Weight: 228.45

Specific Gravity: 0.877

HMIS Key: 2-2-0-X

Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions

Formula: C13H28OSi

Refractive Index: 1.4640

Application: Undergoes Pd-catalyzed cross-coupling with activated aromatic iodides.1
Stable silanol for cross-coupling vinylations.2,3,4
Vinyl silanols cross-couple w/ aryl triflates and nonaflates.5
Potassium salts of silanols cross-couple in absence of fluoride.6

Reference: 1. Denmark, S. et al. Org. Syn. 2005, 81, 42.
2. Denmark, S. E.; Sweis, R. F. J. Am. Chem. Soc. 2001, 123, 6439.
3. Denmark, S. E.; Pan, W. J. Organomet. Chem. 2002, 653, 98.
4. Denmark, S. E.; Wehrli, D. Org. Lett. 2000, 2, 565.
5. Denmark, S. E.; Sweis, R. F. Org. Lett. 2002, 4, 3771.
6. Denmark, S. E.; Kallemeyn, J. M. J. Am. Chem. Soc. 2006, 128, 15958.

Fieser: