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- HMIS 3-4-1-X
- Molecular Formula C4H9ClSi
- Molecular Weight (g/mol) 120.66
- TSCA No
- Boiling Point (˚C/mmHg) 103°
- Density (g/mL) 0.985
- Flash Point (˚C) 2°C (36°F)
- Refractive Index @ 20˚C 1.4500
Review of synthetic utility.1
!ntermediate for enoxysilacyclobutanes.2
Precursor to various aryl and alkenylsilacyclobutanes suitable as a nucleophile in silicon-based cross-coupling.3
1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 166-170.
2. Denmark, S. et al. J. Am. Chem. Soc. 1994, 116, 7026.
3. Denmark, S. E.; Sweis, R. F. Acc. Chem. Res. 2002, 35, 835.
Silane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Silicon Chemistry, Articles
Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products