p-CHLOROPHENYLTRIMETHYLSILANE

Product Code: SIC2334.0
CAS No: 10557-71-8
SDS Sheets: EU | US
Pack Size
Quantity
Price
 
25 g
$116.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    3-2-0-X
  • Molecular Formula

    C9H13ClSi
  • Molecular Weight (g/mol)

    184.74
  • TSCA

    Yes
  • Boiling Point (˚C/mmHg)

    206-7°
  • Density (g/mL)

    0.996
  • Flash Point (˚C)

    49°C (120°F)
  • Melting Point (˚C)

    0.0°
  • Refractive Index @ 20˚C

    1.5067

Additional Properties

  • Hydrolytic Sensitivity

    4: no reaction with water under neutral conditions
  • Safety

  • Packaging Under

    Nitrogen
  • Arylsilane Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    p-Chlorophenyltrimethylsilane; (4-Chlorophenyl)trimethyl1-chloro-3-(trimethylsilyl)benzene benzene; 1-Chloro-4-(trimethylsilyl)-silane

  • Dipole moment: 1.70 debye
  • Vapor pressure, 120 °C: 50 mm
  • Introduction of the p-chlorophenyl group
  • Potential for formation of triaryls
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
  • Silicon Chemistry, Articles

    Silicon-Based Formation of Carbon-Carbon Bonds – Larson

    Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products