O-(t-BUTYLDIMETHYLSILYL)HYDROXYLAMINE

Product Code: SIB1963.0
CAS No: 41879-39-4
SDS Sheets: EU | US
Pack Size
Quantity
Price
 
10 g
$370.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    3-2-1-X
  • Molecular Formula

    C6H17NOSi
  • Molecular Weight (g/mol)

    147.29
  • Purity (%)

    92%
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    154-7°
  • Flash Point (˚C)

    54 °C
  • Melting Point (˚C)

    63-4°

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water
  • Application

    Review of synthetic utility.1
    Reacts with aldehydes and ketones to form protected oximes.2
    Can be used to generate nitrosoalkenes in the absence of nucleophiles.3

    Fieser

    F&F: Vol. 2, p 85.

    Reference

    1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 124-125.
    2. Denmark, S. E. et al. J. Org. Chem. 1984, 49, 4741.
    3. Denmark, S. E.; Dappen, M. S. J. Org. Chem. 1984, 49, 798.

    Safety

  • Packaging Under

    Nitrogen