O-(t-BUTYLDIMETHYLSILYL)HYDROXYLAMINE

Product Code: SIB1963.0
CAS No: 41879-39-4
SDS Sheets: EU | US
Pack Size
Quantity
Price
 
10 g
$370.00

Prices listed are EXW price (Morrisville, PA US) in USD. Prices vary depending on currency and Incoterms.

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    3-2-1-X
  • Molecular Formula

    C6H17NOSi
  • Molecular Weight (g/mol)

    147.29
  • Purity (%)

    92%
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    154-7°
  • Flash Point (˚C)

    54 °C
  • Melting Point (˚C)

    63-4°

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water
  • Application

    Review of synthetic utility.1
    Reacts with aldehydes and ketones to form protected oximes.2
    Can be used to generate nitrosoalkenes in the absence of nucleophiles.3

    Fieser

    F&F: Vol. 2, p 85.

    Reference

    1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 124-125.
    2. Denmark, S. E. et al. J. Org. Chem. 1984, 49, 4741.
    3. Denmark, S. E.; Dappen, M. S. J. Org. Chem. 1984, 49, 798.

    Safety

  • Packaging Under

    Nitrogen