To search by structure, left click in the box below to display the chemdraw toolbar. Then, draw the chemical structure of interest in the box using the toolbar. When your structure is complete, click “Search by Name” or “Search by SMILES” to generate the product name or SMILES respectively. This feature will search within the Gelest product database for matching chemical names or SMILES. Note: In cases where Gelest uses alternate chemical names, it may be necessary to search for the product of interest by its CAS#.
All structures are computer generated. Please rely on the product data below for placing your order. If you see any errors in structures, please email customer service so that they can be addressed.
BIS(TRIMETHYLSILYLMETHYL)AMINE
Alternative Name: 2,2,6,6-TETRAMETHYL-4-AZA-2,6-DISILAHEPTANE
Specific Gravity: 0.7864
Flashpoint: 33°C (91°F)
HMIS Key: 2-3-0-X
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
Formula: C8H23NSi2
Refractive Index: 1.4267
Application: Opens epoxides with high regioselectivity.1
Forms imine with formaldehyde that does not readily trimerize.2 This aldimine can be used to form ?-lactams.3,4
Reacts with ketones for form imines with (E)-isomer selectivity.5
Reference: 1. Constantieux, T. et al. Synlett 1998, 510.
2. Capperucci, A. et al. J. Organomet. Chem. 1993, 458, C1.
3. Palomo, C. et al. Ang. Chem., Int. Ed. Engl. 1996, 35, 1239.
4. Palomo, C. et al. J. Chem. Soc., Chem. Commun. 1997, 233.
5. Palomo, C. et al. J. Org. Chem. 1997, 62, 2070.
Fieser:
Silanes
Silanes