BIS(TRIMETHYLSILYLMETHYL)AMINE

Product Code: SIB1863.3
CAS No: 17882-91-6
SDS Sheets: EU | US
Pack Size
Quantity
Price
 
5 g
$153.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Synonyms

    2,2,6,6-TETRAMETHYL-4-AZA-2,6-DISILAHEPTANE
  • HMIS

    2-3-0-X
  • Molecular Formula

    C8H23NSi2
  • Molecular Weight (g/mol)

    189.45
  • Purity (%)

    95%
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    171°
  • Density (g/mL)

    0.7864
  • Flash Point (˚C)

    33 °C
  • Refractive Index @ 20˚C

    1.4267

Additional Properties

  • Hydrolytic Sensitivity

    4: no reaction with water under neutral conditions
  • Application

    Opens epoxides with high regioselectivity.1
    Forms imine with formaldehyde that does not readily trimerize.2 This aldimine can be used to form ?-lactams.3,4
    Reacts with ketones for form imines with (E)-isomer selectivity.5

    Reference

    1. Constantieux, T. et al. Synlett 1998, 510.
    2. Capperucci, A. et al. J. Organomet. Chem. 1993, 458, C1.
    3. Palomo, C. et al. Ang. Chem., Int. Ed. Engl. 1996, 35, 1239.
    4. Palomo, C. et al. J. Chem. Soc., Chem. Commun. 1997, 233.
    5. Palomo, C. et al. J. Org. Chem. 1997, 62, 2070.

    Safety

  • Packaging Under

    Nitrogen