N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE

Product Code: SIB1859.0
CAS No: 22737-37-7
Pack Size
Quantity
Price
 
10 g
$182.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    2-3-1-X
  • Molecular Formula

    C6H19NOSi2
  • Molecular Weight (g/mol)

    177.40
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    78-9° / 100
  • Density (g/mL)

    0.830
  • Flash Point (˚C)

    28°C (82°F)
  • Refractive Index @ 20˚C

    1.4110

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water
  • Application

    Review of synthetic utility.1
    Lithiated derivative reacts w/ aldehydes and ketones to give hydroxyimines.2,3

    Fieser

    F&F: Vol. 6, p 58.

    Reference

    1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 75-76.
    2. King, F. D. et al. J. Chem. Soc., Chem. Commun. 1978, 351.
    3. Hoffmann, R. V.; Buntain, G. A. Synthesis, 1987, 831.

    Safety

  • Packaging Under

    Nitrogen