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Silane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Boiling Point: 70° / 15
Molecular Weight: 150.30
Specific Gravity: 0.949
Flashpoint: 65°C (149°F)
HMIS Key: 2-2-1-X
Hydrolytic Sensitivity: 3: reacts with aqueous base
Refractive Index: 1.5040
Application: Intermediate for aminosubstituted vinylsilanes and pyrollidones.1
Useful for the preparation of benzyldimethylsilyl derivatives capable of cross-coupling reactions.2
Reference: 1. Mlyra, K. et al. Org. Lett. 2000, 2, 385.
2. Singh, R.; Singh, G. C.; Ghosh, S.K. Eur. J. Org. Chem. 2007, 5376.