1631-70-5

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BENZYLDIMETHYLSILANE

Product Code: SIB0964.0

Cas No: 1631-70-5

R&D quantities:

10 g
$94.00
Silane Cross-Coupling Agent

The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

Benzyldimethylsilane; Benzyldimethylsilylhydride
  • Useful for the preparation of benzyldimethylsilyl derivatives capable of cross-coupling reactions
  • Intermediate for aminosubstituted vinylsilanes and pyrollidones
  • Afford latent reactive group on silicon in benzyldimethylsilyl derivatives
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
  • Boiling Point: 70° / 15

    Molecular Weight: 150.30

    Specific Gravity: 0.949

    Flashpoint: 65°C (149°F)

    HMIS Key: 2-2-1-X

    Hydrolytic Sensitivity: 3: reacts with aqueous base

    Formula: C9H14Si

    Refractive Index: 1.5040

    TSCA: TSCA

    Application: Intermediate for aminosubstituted vinylsilanes and pyrollidones.1
    Useful for the preparation of benzyldimethylsilyl derivatives capable of cross-coupling reactions.2

    Reference: 1. Mlyra, K. et al. Org. Lett. 2000, 2, 385.
    2. Singh, R.; Singh, G. C.; Ghosh, S.K. Eur. J. Org. Chem. 2007, 5376.

    Fieser: