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- HMIS 2-2-1-X
- Molecular Formula C9H14Si
- Molecular Weight (g/mol) 150.3
- TSCA Yes
- Boiling Point (˚C/mmHg) 70° / 15
- Density (g/mL) 0.949
- Flash Point (˚C) 65°C (149°F)
- Refractive Index @ 20˚C 1.5040
Intermediate for aminosubstituted vinylsilanes and pyrollidones.1
Useful for the preparation of benzyldimethylsilyl derivatives capable of cross-coupling reactions.2
1. Mlyra, K. et al. Org. Lett. 2000, 2, 385.
2. Singh, R.; Singh, G. C.; Ghosh, S.K. Eur. J. Org. Chem. 2007, 5376.
Silane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Silicon Chemistry, Articles
Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products