Pack Size
Quantity
Price
 
10 g
$113.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    2-2-1-X
  • Molecular Formula

    C9H14Si
  • Molecular Weight (g/mol)

    150.3
  • Purity (%)

    97%
  • TSCA

    Yes
  • Boiling Point (˚C/mmHg)

    70° / 15
  • Density (g/mL)

    0.949
  • Flash Point (˚C)

    65 °C
  • Refractive Index @ 20˚C

    1.5040

Additional Properties

  • Hydrolytic Sensitivity

    3: reacts with aqueous base
  • Application

    Intermediate for aminosubstituted vinylsilanes and pyrollidones.1
    Useful for the preparation of benzyldimethylsilyl derivatives capable of cross-coupling reactions.2

    Reference

    1. Mlyra, K. et al. Org. Lett. 2000, 2, 385.
    2. Singh, R.; Singh, G. C.; Ghosh, S.K. Eur. J. Org. Chem. 2007, 5376.

    Safety

  • Packaging Under

    Nitrogen
  • Silane Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    Benzyldimethylsilane; Benzyldimethylsilylhydride

  • Useful for the preparation of benzyldimethylsilyl derivatives capable of cross-coupling reactions
  • Intermediate for aminosubstituted vinylsilanes and pyrollidones
  • Afford latent reactive group on silicon in benzyldimethylsilyl derivatives
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
  • Silicon Chemistry, Articles

    Silicon-Based Formation of Carbon-Carbon Bonds – Larson

    Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products