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AMINOMETHYLTRIMETHYLSILANE
Boiling Point: 94-5°
Molecular Weight: 103.24
Alternative Name: (TRIMETHYLSILYL)METHYLAMINE
Specific Gravity: 0.7697
Flashpoint: 9°C (48°F)
HMIS Key: 3-4-0-X
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
Formula: C4H13NSi
Refractive Index: 1.4168
Application: Reacts with nitrourea to form corresponding ?-silylurea.1
Forms imines which when reacted with fluoride ion generate 2-aza-allylanion chemistry.2,3,4
Form imines which are precursors to imidazolidines.5,6
Reference: 1. Seyferth, D. et al. J. Organomet. Chem. 1972, 44, 279.
2. Achiwa, K. et al. Chem. Lett. 1984, 2041.
3. Tsuge, O. et al. Bull. Chem. Soc. Jpn. 1986, 59, 2537.
4. Imai, N. et al. Chem. Pharm. Bull. 1987, 35, 2085.
5. Achiwa, K.; Sekiya, M. Chem. Lett. 1981, 1213.
6. Achiwa, K. et al. Chem. Pharm. Bull. 1983, 31, 3939.
Additional Properties: Hygroscopic
Silanes