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TRIMETHYLALUMINUM, 1M in heptane (10-11 wt%)

Product Code: OMAL086.2

Cas No: 75-24-1

13 kg
1.5 kg

EINECS Number: 200-853-0

Specific Gravity: 0.688

Flashpoint: -4°C (25°F)

HMIS Key: 3-4-2-X

Hydrolytic Sensitivity: 9: reacts extremely rapidly with atmospheric moisture - may be pyrophoric - glove box or sealed system required

Formula: C3H9Al


Application: Used in the enantioselective addition to aldehydes and ketones.1
Employed in the selective protection of aldehydes in the presence of ketones and of ketones in the presence of esters.2

Reference: 1. Carbohydrates: Tools for Stereoselective Synthesis, 2013, 293.
2. Barrios, F. J.; Springer, B. C.; Colby, D. A. Org. Lett. 2013, 15, 3082.

Fieser: F&F: Vol. 8, p 508; Vol. 15, p 341; Vol. 17, p 372.