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TRIETHYLGERMANE
Boiling Point: 122-3°
Molecular Weight: 160.78
Specific Gravity: 1.004
Flashpoint: 5°C (41°F)
HMIS Key: 3-4-1-X
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Formula: C6H16Ge
Refractive Index: 1.4382
Application: Hydrogermylates alkylpropiolates to give triethylgermylacrylates.1
Regioselective addition to alkynes gives (E) vinylgermanes.2
Catalyst for polymerization of ?-olefins.3
Precursor for germanium deposition at 300°.4
Reference: 1. Dimens, V. et al. J. Organomet. Chem. 1992, 435, 257.
2. Esteruelas, M.A. et al. Organometallics 1999, 18, 2267.
3. Shearer Jr., N. H.; Coover Jr., H. W. U.S. Patent 2,925,409, 1960.
4. Chen, J. et al. J. Vac. Sci. Tech., A 1997, 15, 1140.
Germanium Compounds