TRICHLOROGERMANE

Product Code: GET8150
CAS No: 1184-65-2
SDS Sheets: EU | US
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Quantity
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10 g
$355.00
100 g
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Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    214-673-5
  • HMIS

    3-4-2-X
  • Molecular Formula

    HCl3Ge
  • Molecular Weight (g/mol)

    179.97
  • TSCA

    Yes
  • Boiling Point (˚C/mmHg)

    75
  • Density (g/mL)

    1.930
  • Density Temperature (˚C)

    25
  • Flash Point (˚C)

    12
  • Melting Point (˚C)

    -71°

Additional Properties

  • Hydrolytic Sensitivity

    8: reacts rapidly with moisture, water, protic solvents
  • Application

    Pure GeCl2 may be provided by cooling to -30° and pulling vacuum.1,2
    Complex with 2 moles ether reduces nitro compounds and ferric chloride.3,4
    Hydrogermylates olefins without catalyst.5,6
    Undergoes superacid reactions with aromatics.7,8

    Reference

    1. Schwarz, R. et al. Z. Anor. Allg. Chem. 1954, 275, 1.
    2. Brauer, G. Handbook of Preparative Inorganic Chemistry, 717, Academic, 1963.
    3. Craddock, S. et al. Inorg. Chem. 1967, 6, 1751.
    4. Creemers, H. et al. J. Organomet. Chem. 1967, 7, 237.
    5. Lesbre, M. et al. The Organic Compounds of Germanium, 223, Wiley, 1971.
    6. Wolfsberger, W. J. Praktische Chem. 1992, 334, 453.
    7. Kolosnikov, S. Main Group Metal Chem. 1989, 12, 305.
    8. Kolosnikov, S. Chem. Abstr. 110, 114984u; Izv. Akad. Nauk. Ser. Khim. 1988, 3, 666.

    Safety

  • Packaging Under

    Nitrogen
  • Publications & Technical Reports