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Boiling Point: 181-2°
Molecular Weight: 200.85
Specific Gravity: 1.000
Flashpoint: 48°C (118°F)
HMIS Key: 2-3-0-X
Hydrolytic Sensitivity: 1: no significant reaction with aqueous systems
Refractive Index: 1.4594
Application: Yields amorphous GeC alloys on pyrolysis.1
Irradiation of benzene solutions with Fe(CO)5 gives E-propenyl isomer.2
Reacts with unsaturated compounds.3 - e.g. with EtO2CN=NCO2Et forms Et3GeCH=CH2N(CO2Et)NHCO2Et
Reacts with amines and aldehydes to form homoallylic amines.4
Reference: 1. Morancho, R. Proc. Eur. Con. Chem. Vap. Dep., ed R. Porat, Iscar , p. 381, 1987; Chem. Abstr. 113, 101763h.
2. Mizuno, K. et al. Chem. Express 1992, 7, 209.
3. Laporterie, A. et al. J. Organomet. Chem. 1975, 101, 187.
4. Akiyama, T.; Iwai, Y. Synlett 1998, 273.