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SCANDIUM TRIFLUOROMETHANESULFONATE
Product data and descriptions listed are typical values, not intended to be used as specification.
Alternative Name: SCANDIUM TRIFLATE
HMIS Key: 3-0-0-X
Hydrolytic Sensitivity: 6: forms irreversible hydrate
Formula: C3F9O9S3Sc
TSCA: No
Application: Catalyzes highly enantioselective Mannich-type reactions.1,2,3
Acylation catalyst.4
Reference: 1. Kobayashi, S. et al. Synlett 1993, 472.
2. Kobayashi, S. et al. J. Am. Chem. Soc. 2002, 124, 5640.
3. Kobayashi, S. et al. Org. Lett. 2002, 4, 143.
4. Ishihara, K. et al. J. Org. Chem. 1996, 61, 4560.
Metal-Organics
Metal-Organics
Specialty Chemicals: Metal Trifluoromethanesulfonate Catalysis in Organic Synthesis – DePinto