SCANDIUM TRIFLUOROMETHANESULFONATE

Product Code: CXSC083
CAS No: 144026-79-9
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144026-79-9
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Price
 
1 g
$74.00
5 g
$291.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Synonyms

    SCANDIUM TRIFLATE
  • HMIS

    3-0-0-X
  • Molecular Formula

    C3F9O9S3SC
  • Molecular Weight (g/mol)

    492.16
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    NA
  • Melting Point (˚C)

    >300°

Additional Properties

  • Hydrolytic Sensitivity

    6: forms irreversible hydrate

    • Application

    Catalyzes highly enantioselective Mannich-type reactions.1,2,3
    Acylation catalyst.4

    Reference

    1. Kobayashi, S. et al. Synlett 1993, 472.
    2. Kobayashi, S. et al. J. Am. Chem. Soc. 2002, 124, 5640.
    3. Kobayashi, S. et al. Org. Lett. 2002, 4, 143.
    4. Ishihara, K. et al. J. Org. Chem. 1996, 61, 4560.

    Safety

  • Packaging Under

    Nitrogen

    • Metal-Organic Chemistry, Applied Chemistry & Physics

    Specialty Chemicals: Metal Trifluoromethanesulfonate Catalysis in Organic Synthesis – DePinto

    Metal trifluoromethanesulfonate catalysts, or metal triflates, show advantages in their strong Lewis acidity and their increased tolerance for protic solvents and water, which can result in by-products of the chemical reaction of interest. In addition, metal triflates are generally considered to be environmentally friendly catalysts. This mini-review will present some examples of the applications of various metal triflates in synthetic organic chemistry. Click here for product information on metal triflates.