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SCANDIUM TRIFLUOROMETHANESULFONATE
Alternative Name: SCANDIUM TRIFLATE
HMIS Key: 3-0-0-X
Hydrolytic Sensitivity: 6: forms irreversible hydrate
Formula: C3F9O9S3Sc
Application: Catalyzes highly enantioselective Mannich-type reactions.1,2,3
Acylation catalyst.4
Reference: 1. Kobayashi, S. et al. Synlett 1993, 472.
2. Kobayashi, S. et al. J. Am. Chem. Soc. 2002, 124, 5640.
3. Kobayashi, S. et al. Org. Lett. 2002, 4, 143.
4. Ishihara, K. et al. J. Org. Chem. 1996, 61, 4560.
Metal-Organics
Metal-Organics
Specialty Chemicals: Metal Trifluoromethanesulfonate Catalysis in Organic Synthesis – DePinto