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ZIRCONIUM t-BUTOXIDE
Boiling Point: 70° / 2
Melting Point: 2-3°
Molecular Weight: 383.68
Specific Gravity: 0.96
Flashpoint: 85°C (185°F)
HMIS Key: 2-2-1-X
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Formula: C16H36O4Zr
Application: Employed in CVD of ZrO2.1
Couples carboxylic acids to aluminum (native oxide) surfaces.2
Reagent for preparation of tin(ll) and lead(ll) heterometallic alkoxides.3
Key component of catalyst for the enantioselective reaction of enol silyl ethers with aldimines.4
Reference: 1. Gould, B. et al. J. Mater. Chem. 1994, 4, 1815.
2. Aronoff, Y. et al. J. Am. Chem. Soc. 1997, 119, 259.
3. Teff, D. et al. Inorg. Chem. 1996, 35, 2981.
4. Ishitani, H. et al. J. Am. Chem. Soc. 2000, 122, 8180.
Additional Properties: Vapor pressure, 102°: 9.46 mm?Hvap: 14.8 kcal/moleDecomposes >100°Vapor pressure, 26°: 0.06 mmVapor pressure, 52°: 0.46 mmVapor pressure, 75°: 2.20 mm
Silanes
Silanes
CVD Materials (Co, Zr, Ru, Hf, Ta)
Organosilicon & Metal-organic Precursors for Microelectronics & Optoelectronics