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VANADIUM(IV) OXIDE BIS(2,4-PENTANEDIONATE)
EINECS Number: 221-590-8
Alternative Name: VANADYL ACETYLACETONATE
Specific Gravity: 1.52 - 1.74
HMIS Key: 2-1-1-X
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
Application: Forms electrically conductive VO2 coatings.1
Stereospecific oxidation of olefins in combination with t-butylhydroperoxide.2,3
Catalyst for preparation of amine oxides.4
In combination with BiPh3 yields bismuth vanadate catalysts by CVD.5
Reference: 1. Serbinov, I. Thin Solid Films 1975, 27, 171.
2. Sharpless, K. J. Am. Chem. Soc. 1973, 95, 6136.
3. Rossiter, B. et al. Tetrahedron Lett. 1979, 4733.
4. Sheng, M. et al. F&F: Vol. 2, p 456; J. Org. Chem. 1968, 33, 588.
5. Barreca, D. et al. Chem. Mater. 1999, 11, 255.
Additional Properties: Solubility, water: 13 g/l19.1-19.5% VGreen-BlueMethanol 64 g/lCatalyst for the polymerization of olefins