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MAGNESIUM METHYL CARBONATE, 2M in dimethylformamide (22-25 wt%)

Product Code: AKM506

Cas No: 4861-79-4

100 g

EINECS Number: 225-466-4

Alternative Name: Stiles' Reagent

Specific Gravity: 1.103

Flashpoint: 58°C (136°F)

HMIS Key: 3-2-1-X

Hydrolytic Sensitivity: 7: reacts slowly with moisture/water

Formula: C3H6MgO4·XCO2


Application: Mild carboxylating agent for nitro and carbonyl compounds.1,2

Reference: 1. Finkbeiner, H. J. Org. Chem. 1963, 28, 215.
2. Cate, L. A. Synthesis 1983, 385.

Fieser: F&F: Vol. 1, p 631.