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EINECS Number: 241-616-1
Melting Point: 209-213°
Molecular Weight: 1037.49
Alternative Name: EUROPIUM FOD
HMIS Key: 2-1-0-X
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
Application: Improves rate and endo-selectivity of cyclopentadiene with allenic esters in Diels-Alder reactions.1,2
NMR shift reagent.3
Catalyzes the addition of silyl ketene acetals to aldehydes with high diastereoselectivity.4
Reference: 1. Gandhi, R. et al. J. Chem. Soc., Chem. Comm. 1988, 1074.
2. Alonso, I. et al. J. Org. Chem. 1993, 58, 3231.
3. Wenzel, T. et al. J. Am. Chem. Soc. 1980, 102, 5903.
4. Terada, M. et al. Chem. Lett. 1992, 21, 29.
Fieser: F&F: Vol. 12, p 559; Vol. 15, p. 355.