17631-68-4

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EUROPIUM(III) 6,6,7,7,8,8,8-HEPTAFLUORO-2,2-DIMETHYL-3,5-OCTANEDIONATE

Product Code: AKE287

Cas No: 17631-68-4

R&D quantities:

1 g
$49.00
5 g
$193.00

Interested in a Commercial Order?

EINECS Number: 241-616-1

Melting Point: 209-213°

Molecular Weight: 1037.49

Alternative Name: EUROPIUM FOD

HMIS Key: 2-1-0-X

Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions

Formula: C30H30EuF21O6

TSCA: TSCA

Application: Improves rate and endo-selectivity of cyclopentadiene with allenic esters in Diels-Alder reactions.1,2
NMR shift reagent.3
Catalyzes the addition of silyl ketene acetals to aldehydes with high diastereoselectivity.4

Reference: 1. Gandhi, R. et al. J. Chem. Soc., Chem. Comm. 1988, 1074.
2. Alonso, I. et al. J. Org. Chem. 1993, 58, 3231.
3. Wenzel, T. et al. J. Am. Chem. Soc. 1980, 102, 5903.
4. Terada, M. et al. Chem. Lett. 1992, 21, 29.

Fieser: F&F: Vol. 12, p 559; Vol. 15, p. 355.