EUROPIUM(III) 6,6,7,7,8,8,8-HEPTAFLUORO-2,2-DIMETHYL-3,5-OCTANEDIONATE

Product Code: AKE287
CAS No: 17631-68-4
SDS Sheets: EU | US
Pack Size
Quantity
Price
 
1 g
$59.00
5 g
$232.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    241-616-1
  • Synonyms

    EUROPIUM FOD
  • HMIS

    2-1-0-X
  • Molecular Formula

    C30H30EuF21O6
  • Molecular Weight (g/mol)

    1037.49
  • TSCA

    Yes
  • Boiling Point (˚C/mmHg)

    NA
  • Melting Point (˚C)

    209-213°

Additional Properties

  • Hydrolytic Sensitivity

    4: no reaction with water under neutral conditions
  • Application

    Improves rate and endo-selectivity of cyclopentadiene with allenic esters in Diels-Alder reactions.1,2
    NMR shift reagent.3
    Catalyzes the addition of silyl ketene acetals to aldehydes with high diastereoselectivity.4

    Fieser

    F&F: Vol. 12, p 559; Vol. 15, p. 355.

    Reference

    1. Gandhi, R. et al. J. Chem. Soc., Chem. Comm. 1988, 1074.
    2. Alonso, I. et al. J. Org. Chem. 1993, 58, 3231.
    3. Wenzel, T. et al. J. Am. Chem. Soc. 1980, 102, 5903.
    4. Terada, M. et al. Chem. Lett. 1992, 21, 29.

    Safety

  • Packaging Under

    Nitrogen