ALUMINUM t-BUTOXIDE, tech

Product Code: AKA030
CAS No: 556-91-2
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556-91-2
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Quantity
Price
 
10 g
$71.00
50 g
$278.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    209-146-1
  • HMIS

    2-2-0-X
  • Molecular Formula

    C12H27AlO3
  • Molecular Weight (g/mol)

    246.32
  • Purity (%)

    95%
  • TSCA

    Yes
  • Delta H Vaporization (kJ/mol)

    21.6 kcal/mole
  • Boiling Point (˚C/mmHg)

    156° / 2
  • Melting Point (˚C)

    241-6°

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water

    • Application

    Catalyst for Oppenauer oxidation of alcohols to ketones.1,2
    Reacts with AlCl3 to form Al2O3 in non-hydrolytic reaction.3

    Fieser

    F&F: Vol. 1, p 23; Vol. 2, p. 21.

    Reference

    1. Djerassi, C. "The Oppenauer Oxidation," Org. React. 1951, 6, 207.
    2. Oppenauer, R. Org. Syn. 1955, Coll. Vol. 3, 207.
    3. Acosta, S. et al. J. Non-Cryst. Solids 1994, 170, 234.

    Safety

  • Packaging Under

    None