ALUMINUM t-BUTOXIDE, tech

Product Code: AKA030
CAS No: 556-91-2
SDS Sheets: EU | US
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556-91-2
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Pack Size
Quantity
Price
 
10 g
$71.00
50 g
$278.00

Prices listed are EXW price (Morrisville, PA US) in USD. Prices vary depending on currency and Incoterms.

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    209-146-1
  • HMIS

    2-2-0-X
  • Molecular Formula

    C12H27AlO3
  • Molecular Weight (g/mol)

    246.32
  • Purity (%)

    95%
  • TSCA

    Yes
  • Delta H Vaporization (kJ/mol)

    21.6 kcal/mole
  • Boiling Point (˚C/mmHg)

    156/2
  • Melting Point (˚C)

    241-6°

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water

    • Application

    Catalyst for Oppenauer oxidation of alcohols to ketones.1,2
    Reacts with AlCl3 to form Al2O3 in non-hydrolytic reaction.3

    Fieser

    F&F: Vol. 1, p 23; Vol. 2, p. 21.

    Reference

    1. Djerassi, C. "The Oppenauer Oxidation," Org. React. 1951, 6, 207.
    2. Oppenauer, R. Org. Syn. 1955, Coll. Vol. 3, 207.
    3. Acosta, S. et al. J. Non-Cryst. Solids 1994, 170, 234.

    Safety

  • Packaging Under

    None