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To search by structure, left click in the box below to display the chemdraw toolbar. Then, draw the chemical structure of interest in the box using the toolbar.   When your structure is complete, click “Search by Name” or “Search by SMILES” to generate the product name or SMILES respectively.  This feature will search within the Gelest product database for matching chemical names or SMILES.  Note: In cases where Gelest uses alternate chemical names, it may be necessary to search for the product of interest by its CAS#.

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Download the Technical Brochure

Alkylsilicates are key building blocks for the cross-coupling reactions of sp3-sp2 and sp3-sp3 carbon centers that were developed by Professor Gary A. Molander at the University of Pennsylvania in 2016.
Cross-coupling of sp3-sp2 carbon centers is particularly important for drug discovery as it has been reported that compounds with lower sp3 fractions have higher rates of attrition in drug development. A few examples of sp3-sp2 cross-couplings reactions between alkylsilicates and p-cyanobromobenzene with Ir/Ni dual catalysis were first reported in 2015 by the Fensterbank group (ACIE, 2015, 54, 11414), but a general synthetic method was not available until 2016. The Molander group at the University of Pennsylvania demonstrated that alkylsilicates undergo sp3-sp2 cross-coupling reactions with a broad range of aryl and alkenyl compounds via a photoredox dual catalysis of ruthenium and nickel. The reaction conditions are mild and suitable for both small-scale lab syntheses and large-scale commercial production. Alkylsilicates are stable solids that can be stored for long periods of time at ambient temperature.

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Silanes

Product Code: SIT8205.0

TRIETHYLAMMONIUM 2-(2-PYRIDYLETHYL)BIS(CATECHOLATO)SILICATE

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Product Details
1843232-66-5

Silanes

Product Code: SIT8204.0

CAS No: 1843232-66-5

TRIETHYLAMMONIUM METHYLBIS(CATECHOLATO)SILICATE

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Silanes

Product Code: SIT8203.0

TRIETHYLAMMONIUM IODOMETHYL BIS(CATECHOLATO)SILICATE

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Product Details
1844886-87-8

Silanes

Product Code: SIT8202.0

CAS No: 1844886-87-8

TRIETHYLAMMONIUM CHLOROMETHYLBIS(CATECHOLATO)SILICATE

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Product Details

Silanes

Product Code: SIT8201.0

TRIETHYLAMMONIUM BIS(CATECHOLATO)ALLYLSILICATE

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Silanes

Product Code: SIT8199.0

TRIETHYLAMMONIUM BENZYLBIS(CATECHOLATO)SILICATE

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Silanes

Product Code: SIT8197.0

TRIETHYLAMMONIUM 3-ACETOXYPROPYLBIS(CATECHOLATO)SILICATE

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Product Details
1844886-91-4/123-9-1

Silanes

Product Code: SID3533.7

CAS No: 1844886-91-4/123-9-1

DIISOPROPYLAMMONIUM 3-PHENYLAMINOPROPYL BIS(CATECHOLATO)SILICATE

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Silanes

Product Code: SID3533.4

DIISOPROPYLAMMONIUM NONAFLUOROHEXYLBIS(CATECHOLATO)SILICATE

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Product Details
Denotes Commercial Product produced on a regular basis for inventory
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SIT8205.0

TRIETHYLAMMONIUM 2-(2-PYRIDYLETHYL)BIS(CATECHOLATO)SILICATE

Product Details

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SIT8204.0

TRIETHYLAMMONIUM METHYLBIS(CATECHOLATO)SILICATE

Product Details

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SIT8203.0

TRIETHYLAMMONIUM IODOMETHYL BIS(CATECHOLATO)SILICATE

Product Details

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SIT8202.0

TRIETHYLAMMONIUM CHLOROMETHYLBIS(CATECHOLATO)SILICATE

Product Details

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SIT8201.0

TRIETHYLAMMONIUM BIS(CATECHOLATO)ALLYLSILICATE

Product Details

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SIT8199.0

TRIETHYLAMMONIUM BENZYLBIS(CATECHOLATO)SILICATE

Product Details

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SIT8197.0

TRIETHYLAMMONIUM 3-ACETOXYPROPYLBIS(CATECHOLATO)SILICATE

Product Details

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SID3533.7

DIISOPROPYLAMMONIUM 3-PHENYLAMINOPROPYL BIS(CATECHOLATO)SILICATE

Product Details

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SID3533.4

DIISOPROPYLAMMONIUM NONAFLUOROHEXYLBIS(CATECHOLATO)SILICATE

Product Details

SIT8205.0

Product Details

1843232-66-5

SIT8204.0

Product Details

SIT8203.0

Product Details

1844886-87-8

SIT8202.0

Product Details

SIT8201.0

Product Details

SIT8199.0

Product Details

SIT8197.0

Product Details

1844886-91-4/123-9-1

SID3533.7

Product Details

SID3533.4

Product Details

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